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Industry and Market Analysis Global Tobacco Industry Trends Declining Cigarette Volumes : Globally, cigarette consumption continues to decrease, particularly in developed countries where smoking rates have been in steady decline for decades

This suggests that 3,5-dimethyl-1-phenylpyrazole having a lower HOMO energy value of 6.213 eV is much more stable making it a good nucleophile compared to nicotine and -nicotyrine which are energetically higher in the HOMO