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22 , 24 , 25 The acidic pH is controlled and maintained at the acid mantle, a thin acidic film at the surface of the SC consisting of sebum, sweat, lactic acid, urocanic acid, fatty acids, and pyrrolidine carboxylic acid

The predominant RNS is nitric oxide radical (NO ) [36], formed in biological tissues from the oxidation of L-arginine to citrulline by nitric oxide synthase [37, 38], and precursor of other two RNS, the peroxynitrite (ONOO ), and the nitrogen dioxide radical ( NO 2 ) (Fig