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In GSH, there is an iso-peptide bond between the gamma-carboxyl group of the GLU side chain and CYS (see Figure 1)
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doi: 10.1016/j.bbagen.2009.07.026
A vial at day 30 is not dramatically different from day 28, but a vial at day 60 has meaningfully less active peptide than one at day 14
